Assessments of ozone depletion as an author, coauthor. Free chlorine cl atoms then react with ozone molecules, taking one oxygen atom to form chlo. Astrochemistry basic processes pdf 63p this note covers the following topics. Cfc molecules are made up of chlorine, fluorine and carbon atoms and are extremely stable. When chlorine nitrate, a chemical that ties up chlorine in an ozonesafe form, was added to the hypothesis, the expected amount of ozone loss decreased.
Ozone could be manufactured, stored, transported to the stratosphere, and released in depleted regions. Know we study about ozone depletion a major problem for all human being. Mar 21, 2020 ozone depletion, gradual thinning of earth s ozone layer in the upper atmosphere caused by the release of chemical compounds containing gaseous chlorine or bromine from industry and other human activities. This bad ozone forms when sunlight initiates chemical reac. Chlorofluorocarbons and ozone depletion american chemical. Others, such as an no 2 molecule, are not quite so reactive and are stable enough to exist for a somewhat longer time. Other less common compounds with an odd number of electronsknown as free radicalsreadily undergo chemical reactions and do not. The earths stratospheric ozone layer plays a critical role in. O 3 depletion leads to the entry of more uv radiation into the troposphere. However, these cause a very nominal contribution to the ozone layer depletion which is near about 1 to 2 percent and therefore these. The composition of our air, air pollutants, concentration terms, protecting the ozone layer, the chapman cycle, antarctic seasonal ozone depletion, energy from combustion, first law of thermodynamics, heat of combustion, catalytic reforming, fuel alternatives, water for life, neutralizing the. Free astrochemistry books download ebooks online textbooks. The ozone layer is mainly found in the lower portion of the stratosphere.
Halogen catalysis of ozone degredation halogens are a chemical family containing fluorine, chlorine, bromine and iodine. Feb 12, 2018 far above earths surface, the ozone layer helps to protect life from harmful ultraviolet radiation. There are also springtime polar tropospheric ozone. Atmospheric chemistry, chemical reactions, and history.
Chemistry of the ozone layer there are natural processes that create and destroy ozone in the stratosphere. Ozone layer and causes, effects and solutions to ozone. The evaporation of surface water through the stomata of leaves increases, which results in the decreased moisture content of the soil. Predictions of significant increases in the incidence of skin cancer resulting from continued use of cfcs spurred international action. It was only until recently, 1990s in fact, that the chemistry of ozone creation and destruction was developed by f. Cl2g 2clg in presence of light effects of ozone depletion.
Free chlorine cl atoms then react with ozone molecules, taking one oxygen atom to form chlorine. Scientific assessment of ozone depletion montreal protocol. The handout, activities, and videos will help students understand the timeline and reasons for the initial development and use of chlorofluorocarbons as refrigerants, but also their eventual banning. Depletion of o3 can increase uv radiation entering earth surface. Ozone depletion, gradual thinning of earth s ozone layer in the upper atmosphere caused by the release of chemical compounds containing gaseous chlorine or bromine from industry and other human activities. Causes of ozone layer depletion and its effects on human. Carbon dioxide is the major contributor to global warming.
This was also the start of intensive research into the chemistry of the atmosphere. When highenergy ultraviolet rays uvc strike an oxygen molecule o. The earths ozone layer ozone layerthe region of the stratosphere containing the bulk of atmospheric ozone. This timeline highlights the average area of the ozone hole between september 7th and october th as observed by nasa spacedbased instruments see colored bars and scale. Chemistry of ozone depletion fire protection association nz. Oct 11, 20 know we study about ozone depletion a major problem for all human being. The properties of ozone layer were explored by the british. The ozone layer was discovered in 19 by the french physicists charles fabry and henri buisson. When chloroflurocarbons go upward and reach at ozone layer the ultraviolet radiation of sun break them and cfcl 3 and chlorine radical is form. The first manmade threat to the ozone layer was noted by harold johnston 1971.
For their work, rowland and molina shared the 1995 nobel prize in chemistry with another atmospheric chemist, paul j. Actually, two types of compounds like nitric oxide and chlorofluorocarbons are responsible for depleting the. Effects of ozone depletion ozone depletion is affecting the human health and environment negatively, as it allows the penetration of uv radiations to reach the earth. Ozone in the troposphere is toxic due to its reactive oxidizing capabilities. This extreme stability allows cfcs to slowly make their way into the stratosphere most molecules decompose before they can cross into the stratosphere from the troposphere. The reaction of these free radicals with ozone disrupts the ozone oxygen cycle, leading to the destruction of stratospheric ozone and the depletion of the ozone layer. Apr 18, 2019 the ozone layer helps to protect life from harmful ultraviolet radiation.
Besides carbon dioxide, other greenhouse gases are methane, water vapour, nitrous oxide, cfcs and ozone. When cfc is released into the atmosphere, they mix with atmospheric. Ozone layer depletion definition, causes, solutions toppr. Front matter ozone depletion, greenhouse gases, and. Adapted for the internet from chlorofluorocarbons and ozone depletion, produced by the american chemical societys national historic chemical landmarks program in 2017. Learn what cfcs are, how they have contributed to the ozone hole, and how the 1989 montreal. The chloroflurocarbons clfc s which is used in air conditioner and a refrigerator is a major cause of ozone depletion.
The ozone layer helps to protect life from harmful ultraviolet radiation. This extreme stability allows cfcs to slowly make their way into the stratosphere most molecules decompose before they can. The antarctic ozone hole, as it came to be known, made depletion of the ozone layer a real and present danger to lawmakers and the public at large. Cfcs destroy the ozone in the stratosphere 15 20 km above the earths surface ozone concentrations are measure in dobsen units, 1 dobsen unit represents 1 molecule of o 3 for every 1 billion air molecules ozone loss is greatest over antarctica where the ozone depletion has been recorded and is. The ozone layer refers to a region of earths stratosphere that absorbs most of the suns uv radiation. Sulfuric acid decomposition chemistry above junge layer in. A presentation about the chemistry of the ozone layer and how cfc affects the thin layer of atmosphere that contains ozone produced by the interaction of ultraviolet light.
Sherwood rowland, mario molina rowlands postdoc at the time, and paul crutzen and in 1995 they received the nobel prize for their work. There are also springtime polar tropospheric ozone depletion. Ozone depletion wikimili, the best wikipedia reader. Chemistry equations for ozone depletion the student room. Ozone depletion consists of two related events observed since the late 1970s. Cfcs destroy the ozone in the stratosphere 15 20 km above the earths surface ozone concentrations are measure in dobsen units, 1 dobsen unit represents 1 molecule of o 3 for every 1 billion air molecules ozone loss is greatest over antarctica where the ozone depletion has been recorded and is commonly referred to as the ozone hole. Ozone depletion also explains much of the observed reduction in stratospheric and upper tropospheric temperatures. One of the main reasons for the widespread concern about depletion of the ozone layer is the anticipated increase in. It contains high concentrations of ozone o3 relative to other parts of the atmosphere. The ozone depletion process replacing lost ozone in the stratosphere the idea is sometimes put forth that humans could compensate for lost global stratospheric ozone by replacing it. At the same time, recent data show that these atmospheric developments are interconnected and in turn profoundly affect climatic conditions. The atomic chlorine and bromine radicals are found in certain stable organic compounds, especially cfcs, which can make their way to the stratosphere because of their low reactivity. Find out what caused the ozone hole, and how the 1989 montreal protocol sought to put an end to ozone depletion.
All of us are aware of how the concern related to depletion of ozone layer and the ozone hole, which also led to the ban of many chemicals such as the chlorofluorocarbon cfc. The above reaction leads to the formation of chlorine and begins a chain reaction thereby causing ozone depletion. Ozone depletion facts and information national geographic. What are the reactions involved for ozone layer depletion in. Ozone layer depletion is one of the major environmental issues which is getting thinner day by day as a result of increasing pollution. The depletion of ozone layer is a global phenomena both in terms of cause and effect. Environmental chemistry lecture notes by asoka marasinghe. There, sunlight could free the chlorine or bromine atoms to form chlorine monoxide or other chemicals, which would deplete upperatmospheric ozone. Ozone formation, ozone depletion studies in the ozone depletion studies in the ultra violet, monoterpenes, the citrus smell. It is found that the ozone layer gets affected by some natural causes that are sunspots and stratospheric winds. Pdf causes of ozone layer depletion and its effects on. The latter phenomenon is referred to as the ozone hole. Environmental chemistry 401 carbon dioxide crosses the delicate proportion of 0.
What are the reactions involved for ozone layer depletion. Ozone depletion events odes in the springtime of the arctic have been frequently observed since the early 1980s, and the correlation between the ozone mixing ratio during the odes and the nitrogen oxides nox concentration is still unclear. Basic ozone layer science ozone layer protection us epa. Pdf atmospheric ozone layer depletion and its impact. Ozone layer depletion is the destruction of ozone gas of upper atmospheric layer stratosphere, caused by substances formed from breakdown of. Depletion of this layer by ozone depleting substances ods will lead to higher uvb levels, which in turn will cause increased skin cancers and cataracts and potential damage. Uv radiations are very harmful and can cause health issues such as skin cancer, ageing. The chemical reactions causing this ozone depletion are primarily based on atomic. Ozone in the stratosphere is necessary to life as we know it because it absorbs energetic uv radiation. The antarctic hole now measures about 9 million square miles, nearly the. Looking back over the scientific investigation of ozone depletion, we can see how the molinarowland hypothesis evolved with new data. The proteins cells in plants undergo harmful mutations, all due to ultraviolet radiations. The ozone depletion phenomenon the ozone depletion. Far above earths surface, the ozone layer helps to protect life from harmful ultraviolet radiation.
Chlorofluorocarbons and ozone depletion answer guide. The chemistry by which cfcs break down ozone is an extremely complicated process. These processes regulate a balance of ozone and form the ozone layer. These advances add to the scientific basis for decisions made by the parties to the montreal protocol. Ozone depletion in the stratosphere and increases in greenhouse gases in the troposphere are both subjects of growing concerneven alarmamong scientists, policymakers, and the public. Free chlorine cl atoms then react with ozone mol ecules, taking one oxygen atom to form chlorine monoxide clo and leaving an oxygen molecule. The chlorofluorocarbon and the halons are potent ozone depletors.
Like an infection that grows more and more virulent, the continentsize hole in earths ozone layer keeps getting bigger and bigger each year since the late 1970s, much of the protective layer of stratospheric ozone above antarctica has disappeared during september, creating what is popularly known as the ozone hole. The following inquirybased student activities are designed for use in high school lesson planning. Free environmental chemistry books download ebooks online. But ozone depleting substances ods are being released in the atmosphere by highflying jets and rockets. The ozone layer lies approximately 1540 kilometers 1025 miles above the earths surface, in the stratosphere. Evidence of ozone depletion in the stratosphere began to appear in the 1980s. The global exchange between ozone and oxygen is on the order of 300 million tons per day. Ozone is unstable and decomposes to molecular oxygen. Compare ozone formation in the free troposphere, in photochemical smog and in the stratosphere. Atmosphere free fulltext influence of the background.
Sulfuric acid h2so4 is the seed molecule for formation of stratospheric sulfate aerosol layer that assists ozone depletion by activation of halogen species. A seasonal decrease, or hole, in the ozone layer above antarctica, first discovered in 1982 and reported in 1985, was the first confirmation of a thinning of the layer. List of books and articles about ozone layer online. Additional copies may be obtained, free of charge, from. Chemistry of ozone depletion cfc molecules are made up of chlorine, fluorine and carbon atoms and are extremely stable. A seasonal decrease, or hole, in the ozone layer above antarctica, first discovered in 1982 and reported in 1985, was. Front matter ozone depletion, greenhouse gases, and climate. The thinning is most pronounced in the polar regions, especially over antarctica. Like an infection that grows more and more virulent, the continentsize hole in earths ozone layer keeps ge. When a cfc is broken down, the chlorine generated is a free radical, which has an. Sep 30, 2019 chemistry of ozone depletion cfc molecules are made up of chlorine, fluorine and carbon atoms and are extremely stable.
National aeronautics and the ozone hole space administratio n. Ozone depletion is the process of destruction of the ozone layer which can cause adverse effects on the living forms by many pollutants releases out from the vehicles, industries etc. A dynamic equilibrium is maintained between the formation and decomposition of ozone. Ozone depletion and climate change environment canada. Some free radicals, such as an oxygen atom, react with another atom or molecule almost immediately. Atmospheric chemistry division at the national center for. These radiations can cause severe diseases in humans such as skin cancer, eye damage and genetic mutations etc 9. It has been found that this protective ozone layer is getting depleted because of the presence of cfc chlorofluorocarbon compounds. The so called hole in ozone layers simply means that above some continents specifically antarctica, asia and parts of south america the mesosphere and stratosphere have lost their original level of ozone content.
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